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Surface Determination: Why Surface Energy and Wettability Are Important

Every material surface has specific physical and chemical properties that determine the success of subsequent process steps. Whether bonding, painting, printing, or coating: stable and reproducible results can only be achieved when the surface, liquid, and application are properly matched.

Plasmatreat helps modify surfaces in a targeted manner and reliably evaluate their properties. A key parameter is surface energy: it describes the energetic conditions at the interface between a solid surface and a liquid and significantly influences wetting behavior.

This page explains the fundamentals of surface determination and shows why testing surfaces before or after plasma treatment is a crucial step for many applications.

What Is Surface Energy?

Surface energy is a key parameter for evaluating solid surfaces. It describes the energetic conditions at the interface and significantly influences the wetting behavior of liquids as well as the resulting adhesion in subsequent processes.

High surface energy generally promotes wetting, while low surface energy can lead to poorer spreading behavior. In industrial surface treatment, it is therefore an important indicator of whether a substrate has been properly prepared for bonding, painting, printing, or coating processes.

Wettability and Adhesion

Wetting describes the behavior of a liquid upon contact with a solid surface. The better a liquid spreads, the higher the wettability generally is. The contact angle is an important measure of this behavior.

Adhesion, on the other hand, describes the quality of bonding between a substrate and a subsequent medium, such as an adhesive, paint, or coating. Wettability and adhesion are closely related but are not identical: good wettability is often an important prerequisite for good adhesion, but it does not replace it.

Plastics, Metals, and Glass

Wetting properties depend heavily on the material.

  • Plastics often have comparatively low surface energy. As a result, liquids tend to wet the surface less effectively, which can compromise process reliability during bonding, printing, or coating.
  • Metals generally have higher surface energy. However, their wettability can be significantly affected by oxidation, contaminants, or storage conditions.
  • Glass is generally highly wettable, but its behavior can be significantly altered by fingerprints, organic residues, or other contaminants.

Why Surface Testing Is Important

Surfaces cannot always be reliably assessed visually. A surface that appears clean to the eye may still be chemically unsuitable for the next process step.

Inspection before or after treatment helps better evaluate surface conditions, make process changes traceable, and improve reproducibility in development, quality assurance, and production.

Connection to Plasma

Plasma treatment is used to specifically modify surfaces and improve their properties for subsequent process steps. These include, among other things, increased wettability and, often, improved adhesion.

If you'd like to learn more about the physical and technological fundamentals of plasma treatment, you'll find a good introduction on the What is Plasma.

How Can a Surface Be Tested?

Various methods are available for evaluating surfaces. The appropriate method depends on the material, the specific application, and the desired measurement accuracy.

Test Inks

Quickly check whether a surface is sufficiently wettable.

AntiCorr® Test Fluids

Quickly evaluate coatings and visualize their protective effect.

Contact Angle Measurement / MSA

Precisely analyze wettability and surface energy.